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What is Biodiesel?

Bio diesel is a diesel fuel substitute produced from renewable sources such as vegetable oils, animal fats, and recycled cooking oils. Chemically, it is defined as the mono alkyl esters derived from renewable sources. Bio diesel is typically produced through the reaction of a vegetable oil with methanol or ethanol in the presence of a catalyst to yield glycerine and bio diesel (chemically called methyl or ethyl esters). Bio diesel can be used in neat form, or blended with petroleum diesel for use in (the) diesel engines.

 Bio diesel has similar physical and chemical properties to petroleum diesel with reference to the operation of a diesel motor.. Its physical and chemical properties as it relates to operation of diesel engines are similar to petroleum based diesel fuels.

 

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Advantages

Environmental

Warrantees

Performance

Myths

Legislation

Advantages of using biodiesel

Bio diesel can be used alone or mixed in any ratio with petroleum diesel fuel, when it is burned, CO2 is released into the atmosphere which is then recycled and absorbed by growing plants which can later be processed into fuel. It produces 80% less carbon dioxide, 100% less sulphur dioxide (major component of acid rain) and up to 75% less exhaust smoke emissions. The flash point of bio diesel is ± 150°C as opposed to petroleum diesel at ± 70°C. It degrades about 4 times faster after spillage and provides significant lubricity improvement over petroleum diesel fuel.

Testing at labs such as Southwest Research Institute, Standyne Automotive and Engineering Testing Services have demonstrated that bio diesel provides significant lubricity improvement over petroleum diesel fuel. Lubricity results of bio diesel and petroleum diesel using the High Frequency Reciprocating Rig test indicate that there is a marked improvement in lubricity when bio diesel is added to conventional diesel fuel, even at blend levels below 1%. Blending bio diesel with diesel fuel accelerates its biodegradability. For example, blends of 20% bio diesel and 80% diesel fuel degraded twice as fast as petroleum diesel. Thus, bio diesel use has demonstrated biodegradability benefits at levels lower than 100%. Simply stated, neat bio diesel degrades as fast as sugar and a 20% blend will degrade twice as fast as petroleum based diesel fuel

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Environmental benefits

Environmental benefits in comparison to petroleum based fuels include:

  • Biodiesel reduces emissions of carbon monoxide (CO) by approximately 50% and carbon dioxide by 78% on a net lifecycle basis because the carbon in biodiesel emissions is recycled from carbon that was already in the atmosphere, rather than being new carbon from petroleum that was sequestered in the earth's crust. (Sheehan, 1998)
  • Biodiesel contains fewer aromatic hydrocarbons: benzofluoranthene: 56% reduction; Benzopyrenes: 71% reduction.
  • Biodiesel reduces by as much as 65% the emission of particulates, small particles of solid combustion products. This reduces cancer risks by up to 94% according to testing sponsored by the Department of Energy.[citationᅠneeded]
  • Biodiesel does produce more nitrogen oxide NOx emissions than petrodiesel, but these emissions can be reduced through the use of catalytic converters. As biodiesel contains no nitrogen, the increase in NOx emissions may be due to the higher cetane rating of biodiesel and higher oxygen content, which allows it to convert nitrogen from the atmosphere into NOx more rapidly. Properly designed and tuned engines may eliminate this increase.
  • Biodiesel has higher cetane rating than petrodiesel, and therefore ignites more rapidly when injected into the engine. It also has the highest energy content of any alternative fuel in its pure form (B100).
  • Biodiesel is biodegradable and non-toxic - tests sponsored by the United States Department of Agriculture confirm biodiesel is less toxic than table salt and biodegrades as quickly as sugar.[citationᅠneeded]
  • In the United States, biodiesel is the only alternative fuel to have successfully completed the Health Effects Testing requirements (Tier I and Tier II) of the Clean Air Act (1990).

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Engine Warranties

Most major engine companies have stated formally that the use of blends up to B20 will not void their parts and workmanship warranties. This includes blends below 20% bio diesel, such as the 2% bio diesel blends that are becoming more common. Several statements from the engine companies are available on the NBB website. It is anticipated that the entire industry will incorporate the ASTM bio diesel standard into their owner's manuals over time. With bio diesel that meets the D-6751 specification, there have been over 45 million miles of successful, problem-free, real-world operation with B20 blends in a wide variety of engines, climates, and applications. The steps taken by the bio diesel industry to work with the engine companies and to ensure that fuel meets the newly accepted ASTM standards provides confidence to users and engine manufacturers that their bio diesel experiences will be positive and trouble-free.

Biodiesel can be used in pure form (B100) or may be blended with petroleum diesel at any concentration in most modern diesel engines. Biodiesel will degrade natural rubber gaskets and hoses in vehicles (mostly found in vehicles manufactured before 1992), although these tend to wear out naturally and most likely will have already been replaced by Viton which is nonreactive to biodiesel. Biodiesel's higher lubricity index compared to petrodiesel is an advantage and can contribute to longer fuel injector life. Biodiesel is a better solvent than petrodiesel and has been known to break down deposits of residue in the fuel lines of vehicles that have previously been run on petroleum. Fuel filters may become clogged with particulates if a quick transition to pure biodiesel is made, as biodiesel cleans the engine in the process. It is, therefore, recommended to change the fuel filter within 600-800 miles after first switching to a biodiesel blend.

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Performance

Successful alternative fuels fulfill environmental and energy security needs without sacrificing operating performance. Operationally, bio diesel blends perform very similar to low sulphur diesel in terms of power, torque, and fuel without major modification of engines or infrastructure.

Bio diesel offers similar power to diesel fuel. One of the major advantages of bio diesel is the fact that it can be used in existing engines and fuel injection equipment with little impact to operating performance. Bio diesel has a higher cetane number than most U.S. diesel fuel. In more than 50 million on-road miles and countless marine and off-road applications, bio diesel shows similar fuel consumption, horsepower, torque, and haulage rates as conventional diesel fuel.

Bio diesel provides significant lubricity improvement over petroleum diesel fuel. Lubricity results of bio diesel and petroleum diesel using industry test methods indicate that there is a marked improvement in lubricity when bio diesel is added to conventional diesel fuel. Even bio diesel levels as low as one percent can provide up to a 65 percent increase in lubricity in distillate fuels.

Compatibility of bio diesel with engine components. The switch to low sulphur diesel fuel has caused most OEMs to switch to components suitable for use with bio diesel, but users should contact their OEM for specific information. In general, pure bio diesel will soften and degrade certain types of elastomers and natural rubber compounds over time. Using high percent blends can impact fuel system components (primarily fuel hoses and fuel pump seals), that contain elastomer compounds incompatible with bio diesel. Manufacturers recommend that natural or butyl rubbers not be allowed to come in contact with pure bio diesel. Blends of B20 or lower have not exhibited elastomer degradation and need no changes. If a fuel system does contain these materials and users wish to fuel with blends over B20, replacement with compatible elastomers is recommended.

Bio diesel in cold weather. Cold weather can cloud and even gel any diesel fuel, including bio diesel. Users of a 20 percent bio diesel blend with #2 diesel will usually experience an increase of the cold flow properties (cold filter plugging point, cloud point, pour point) approximately 2 to 10° Fahrenheit. Precautions employed for petroleum diesel are needed for fuelling with 20 percent blends. Neat (100 percent) bio diesel will gel faster than petrodiesel in cold weather operations. Solutions for winter operability with neat bio diesel are much the same as that for low-sulphur #2 diesel (i.e., blending with #1 diesel, utilization of fuel heaters, and storage of the vehicle in or near a building). These same solutions work well with bio diesel blends, as do the use of cold flow improvement additives.

There are other physical or chemical properties where biodiesel is substantially different from petroleum diesel and where these differences provide significant benefits. Biodiesel has significantly lower sulfur than today’s diesel fuel, while providing a significant increase in lubricity. Most B100 already meets the EPA’s new rule requiring all on-road diesel fuel to contain less than 15 ppm sulfur in 2006. The future 15 ppm diesel—Ultra low sulfur diesel or ULSD—can create lubricity problems as the new refining processes tends to reduce the natural lubricity of diesel. Pure biodiesel, or biodiesel blended with ULSD restores fuel lubricity in levels as low as 1% or 2% biodiesel. Biodiesel also contains 11% oxygen by weight, as well as a slightly higher cetane number, which provides for more complete combustion and a reduction in most emissions.

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Biodiesel Myths and Facts

Myth: Biodiesel is an experimental fuel and has not been thoroughly tested.

Fact: Biodiesel is one of the most thoroughly tested alternative fuels on the market. A number of independent studies have been completed with the results showing biodiesel performs similar to petroleum diesel while benefiting the environment and human health compared to diesel. That research includes studies performed by the U.S. Department of Energy, the U.S. Department of Agriculture, Stanadyne Automotive Corp. (the largest diesel fuel injection equipment manufacturer in the U.S.), Lovelace Respiratory Research Institute, and Southwest Research Institute. Biodiesel is the first and only alternative fuel to have completed the rigorous Health Effects testing requirements of the Clean Air Act. Biodiesel has been proven to perform similarly to diesel in more 50 million successful road miles in virtually all types of diesel engines, countless off-road miles and countless marine hours. Currently more than 300 major fleets use the fuel.

Myth: Biodiesel does not perform as well as diesel.

Fact: One of the major advantages of biodiesel is the fact that it can be used in existing engines and fuel injection equipment with little impact to operating performance. Biodiesel has a higher cetane number than U.S. diesel fuel. In more than 50 million miles of in-field demonstrations, B20 showed similar fuel consumption, horsepower, torque, and haulage rates as conventional diesel fuel. Biodiesel also has superior lubricity and it has the highest BTU content of any alternative fuel (falling in the range between #1 and #2 diesel fuel).

Myth: Biodiesel doesn't perform well in cold weather.

Fact: Biodiesel will gel in very cold temperatures, just as the common #2 diesel does. Although pure biodiesel has a higher cloud point than #2 diesel fuel, typical blends of 20% biodiesel are managed with the same fuel management techniques as #2 diesel. Blends of 5% biodiesel and less have virtually no impact on cold flow.

Myth: Biodiesel causes filters to plug.

Fact: Biodiesel can be operated in any diesel engine with little or no modification to the engine or the fuel system. Pure biodiesel (B100) has a solvent effect, which may release deposits accumulated on tank walls and pipes from previous diesel fuel use. With high blends of biodiesel, the release of deposits may clog filters initially and precautions should be taken to replace fuel filters until the petroleum build-up is eliminated. This issue is less prevalent with B20 blends, and there is no evidence that lower-blend levels such as B2 have caused filters to plug.

Myth: Biodiesel causes degradation of engine gaskets and seals.

Fact: The recent switch to low-sulfur diesel fuel has caused most Original Equipment Manufacturers (OEMs) to switch to components that are also suitable for use with biodiesel. In general, biodiesel used in pure form can soften and degrade certain types of elastomers and natural rubber compounds over time. Using high percent blends can impact fuel system components (primarily fuel hoses and fuel pump seals) that contain elastomer compounds incompatible with biodiesel, although the effect is lessened as the biodiesel blend level is decreased. Experience with B20 has found that no changes to gaskets or hoses are necessary.

Myth: No objective biodiesel fuel formulation standard exists.

Fact: The biodiesel industry has been active in setting standards for biodiesel since 1994 when the first biodiesel taskforce was formed within the American Society for Testing and Materials (ASTM). ASTM approved a provisional standard for biodiesel (ASTM PS 121) in July of 1999. The final specification (D-6751) was issued in December 2001. Copies of specifications are available from ASTM at http://www.astm.org.

Myth: Biodiesel does not have sufficient shelf life.

Fact: Most fuel today is used up long before six months, and many petroleum companies do not recommend storing petroleum diesel for more than six months. The current industry recommendation is that biodiesel be used within six months, or reanalyzed after six months to ensure the fuel meets ASTM specifications (D-6751). A longer shelf life is possible depending on the fuel composition and the use of storage enhancing additives.

 

Myth: Engine warranty coverage would be at risk.

Fact: The use of biodiesel in existing diesel engines does not void parts and materials workmanship warranties of any major US engine manufacturer.

Myth: The U.S. lacks the infrastructure to prevent shortages of the product.

Fact: There are presently more than 14 companies that have invested millions of dollars into the development of the biodiesel manufacturing plants actively marketing biodiesel. Based on existing dedicated biodiesel processing capacity and long-term production agreements, more than 200 million gallons of biodiesel capacity currently exists. Many facilities are capable of doubling their production capacity within 18 months.

Myth: There is no government program to support development of a biodiesel industry.

Fact: The U.S. Department of Agriculture announced in January 2001 the implementation of the first program providing cost incentives for the production of 36 million gallons of biodiesel. Bills supporting the use of biodiesel and ethanol were also introduced to the U.S. Congress in 2003, including one that would set a renewable standard for fuel in the U.S. and one that would give biodiesel a partial fuel excise tax exemption. More than a dozen states have passed favorable biodiesel legislation.

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Legislation

Government is continuously adapting legislation, but as of now you can manufacture 300 000 litres of Biodiesel per annum free of levies and duties. This makes small scale production viable.

The following links will help your planning:

www.stansa.co.za ref: sans 1935:2004 Automotive biodiesel fuel specs

www.sars.co.za Form DA185 annexures 4B2 & 48A

Application to register as biofuel producer

Government Gazette regulations on Biofuels - regulation 8493

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